Az Atletico Madrid, a Barcelona és a Real Madrid is begyűjtötte a három pontot.
| 2014-01-04 16:00 | MALAGA | 0-1 | ATLETICO MADRID Koke 70 |
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| 2014-01-04 18:00 | VALLADOLID | 0-0 | BETIS | |
| 2014-01-04 20:00 | VALENCIA Piatti 42 Feghouli 73 |
2-0 | LEVANTE | |
| 2014-01-04 22:00 | ALMERÍA Dubarbier 14 Verza 28 (11-es) Aleix Vidal 79 |
3-0 | GRANADA | |
| 2014-01-05 12:00 | SEVILLA Vitolo 34 Bacca 55 Rakitic 77 |
3-0 | GETAFE | |
| 2014-01-05 16:00 | BARCELONA Alexis 7, 63, 69 Pedro 16 |
4-0 | ELCHE | |
| 2014-01-05 18:00 | OSASUNA Cejudo 33 |
1-0 | ESPANYOL | |
| 2014-01-05 20:00 | REAL SOCIEDAD Griezmann 43 Rubén Pardo 90 |
2-0 | ATHLETIC BILBAO | |
| 2014-01-06 19:00 | REAL MADRID Benzema 67 Cristiano Ronaldo 82, 90+3 |
3-0 | CELTA VIGO | |
| 2014-01-06 22:00 | RAYO VALLECANO Castillo 66, 90+1 (11-es) |
2-5 | VILLARREAL Uche 10, 58, 64 Perbet 12, 41 |
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