A Real Madrid lett a forduló győztese, kikapott a Barcelona és az Atletico Madrid is.
| 2014-02-21 21:00 | VALLADOLID Javi Guerra 52 |
1-1 | LEVANTE Victor 25 |
| 2014-02-22 16:00 | REAL MADRID Illarramendi 34 Bale 72 Isco 81 |
3-0 | ELCHE |
| 2014-02-22 18:00 | CELTA VIGO Rafinha 59 |
1-1 | GETAFE Lafita 20 piros: L.López 53 |
| 2014-02-22 20:00 | REAL SOCIEDAD Song 32 (öngól) Griezmann 54 Zurutuza 59 |
3-1 | BARCELONA Messi 36 |
| 2014-02-22 22:00 | ALMERÍA | 0-0 | MALAGA |
| 2014-02-23 12:00 | RAYO VALLECANO | 0-1 | SEVILLA Coke 57 piros: Iborra 83 |
| 2014-02-23 17:00 | BETIS piros: Perquis 41 L.Reyes 58 |
0-2 | ATHLETIC BILBAO Muniain 34 (11-es) Guillermo 81 |
| 2014-02-23 19:00 | VALENCIA Paco Alcacer 64 Ruben Vezo 90+1 |
2-1 | GRANADA Piti 47 |
| 2014-02-23 21:00 | OSASUNA Cejudo 6 Armenteros 21 Roberto Torres 42 |
3-0 | ATLETICO MADRID |
| 2014-02-24 22:00 | ESPANYOL J.Córdoba 78 |
1-2 | VILLARREAL Moises 36 Perbet 50 |